Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ3 N,N′,O 1)cobalt(III) nitrate monohydrate
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چکیده
In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octa-hedral geometry. The water mol-ecule and the nitrate anion are located close to an inversion center, and are thus equally disordered by symmetry. The crystal packing is stabilized by inter-molecular O-H⋯O hydrogen bonds involving the uncoordinated water mol-ecule and the free phenol hydroxyl group with the nitrate anion. N-H⋯O hydrogen bonds involving the amino groups and the nitrate anions connect the complex mol-ecules along the c axis.
منابع مشابه
(2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III)
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